Microsoft Expression Web Quick Start Guide
There is no shortage of training materials and samples to get you started using Expression Web. Microsoft also has an Expression Web Quick Start Guide to add to the mix in information and tutorials.
"Get creative in Expression Web now! Download this hands-on lab-including a step-by-step guide, video tutorial and full assets--and start building a standards-based website immediately."
The download gives me a step by step guide and asset files for the basic sample site it introduces, but there no video tutorials included in the download. It may be refering to the video tutorials elsewhere at the Microsoft Expression site. The author of this quick start guide is also a presenter for Total Training, including video training for Expression Web.